PBDTT-DPP is a low band-gap polymer with strong photosensitivity in the range of 650-850 nm, with an onset absorption at 858 nm (Eg = 1.45 eV, near infrared absorption). However, it is less sensitive to visible light in the solar spectrum. For this reason, PBDTT-DPP is an ideal candidate for tandem solar cell structures, having achieved device performances of 8.62% (device structure: ITO/ZnO/P3HT:ICBA/PDOT:PSS/ZnO/PBDTT-DPP:PC71BM/Ag).
Additionally, a single-layer device based on PBDTT-DPP was shown to demonstrate a power conversion efficiency of 6%.[1] PBDTT-DPP also finds application in perovskite solar cells due to its perfect energy level line-ups with perovskites.
Luminosyn™ PBDTT-DPP
Luminosyn™ PBDTT-DPP is now available.
High purity and high molecular weightHPBDTT-DPP is purified by Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere
Batch-specific GPC dataHave confidence in what you are ordering; batch-specific GPC data for your thesis or publications
Large quantity ordersPlan your experiments with confidence with polymers from the same batch
General Information
| Full name | Poly{2,6′-4,8-di(5-ethylhexylthienyl)benzo[1,2-b;3,4-b]dithiophene-alt-5,5"-dibutyloctyl-3,6-bis(5-thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4-dione} |
| Synonyms | PBDT-DPP |
| Chemical formula | (C72H94N2O2S6)n |
| CAS number | 1380582-98-8 |
| HOMO / LUMO | HOMO = -5.30 eV, LUMO = -3.63 eV [1] |
| Classification / Family | Organic semiconducting materials, Low band gap polymers, Organic photovoltaics, Polymer solar cells, Tandem solar cells, Perovskite solar cells. |
| Solubility | Soluble in chloroform, chlorobenzene, dichlorobenzene |
Chemical Structure
MSDS Documentation
PBDTT-DPP MSDS Sheet
Pricing
| Batch | Quantity | Price |
| M1402 | 100 mg | £278.00 |
| M1402 | 250 mg | £557.00 |
| M1402 | 500 mg | £987.00 |
| M1402 | 1 g | £1700.00 |
Batch details
| Batch | Mw | Mn | PDI | Stock Info |
| M1401 | >30,000 | >10,000 | <=3 | Discontinued |
| M1402 | 88,883 | 31,615 | 2.81 | In stock |
Literature and Reviews
- Tandem polymer solar cells featuring a spectrally matched low-bandgap polymer, L. Dou et al., Nat. Photonics 6, 180 (2012); DOI: 10.1038/NPHOTON.2011.356.
- Metal Oxide Nanoparticles as an Electron-Transport Layer in High-Performance and Stable Inverted Polymer Solar Cells, J. You et al., Adv. Mater., 24, 5267–5272 (2012); DOI: 10.1002/adma.201201958.
- Visibly Transparent Polymer Solar Cells Produced by Solution Processing, C. Chen et al., ACS Nano, 6(8), 7185-7190 (2012); DOI: 10.1021/nn3029327.
- High-performance multiple-donor bulk heterojunction solar cells, Y. Yang et al., Nat. Photonics 9, 190–198 (2015); DOI:10.1038/nphoton.2015.9.
To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.
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