1,3-Bis(N-carbazolyl)benzene, known as mCP, with a high triplet energy (ET = 2.91 eV) and a very deep highest occupied molecular orbital (HOMO) level, is often used as host materials for efficient blue phosphorescent light-emitting diodes. Kawamura et al. demonstrated that the photoluminescence internal quantum yield of the blue emitter of FIrpic could approach nearly 100% when doped into the wide energy gap host of mCP [1].
General Information
| CAS number | 550378-78-4 |
| Chemical formula | C30H20N2 |
| Molecular weight | 408.49 g/mol |
| Absorption | λmax 292, 338 nm (in THF) |
| Fluorescence | λem 345, 360 nm (in THF) |
| HOMO/LUMO | HOMO = 5.9 eV, LUMO = 2.4 eV |
| Synonyms | mCP, 1,3-Di(9H-carbazol-9-yl)benzene, N,N′-Dicarbazolyl-3,5-benzene |
| Classification / Family | Carbazole derivatives, Hole transporting materials, Phosphorescent host materials, OLEDs, Organic electronics |
Product Details
| Purity | >99.5% (sublimed) >98.0% (unsublimed) |
| Melting point | 173-178 °C (lit.) |
| Appearance | White powder |
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.
Chemical Structure
Device Structure(s)
| Device structure | ITO(50 nm)/PEDOT:PSS(60 nm)/TAPC(20 nm)/mCP(10 nm)/CbBPCb*(25 nm)/Al(20 nm) [2] |
| Colour | Blue  |
| Max. EQE | ≥ 30% |
| Device structure | ITO/PEDOT:PSS/NPB/mCP/FPt*(1.5 nm)/OXD-7/CsF/Al [3] |
| Colour | White  |
| Max. EQE | 17.5% |
| Max. Power Efficiency | 45 lm W−1 |
| Device structure | ITO(50 nm)/PEDOT:PSS(60 nm)/TAPC(20 nm)/mCP(10 nm)/mCP:BmPyPb*:4CzIPN(25 nm)/TSPO1(35 nm)/LiF(1 nm)/Al(200 nm) [4] |
| Colour | Green  |
| Max. EQE | 28.6% |
| Max. Power Efficiency | 56.6 lm W−1 |
| Device structure | ITO/DNTPD* (60 nm)/NPB (20 nm)/mCP (10 nm)/mCP:FIrpic (25 nm)/CBP:Ir(piq)2acac (5 nm)/BCP (5 nm)/Alq3 (20 nm)/LiF (1 nm)/Al (200 nm) [5] |
| Colour | White |
| EQE@500 cd/m2 | 8.2 % |
| Current Efficiency@500 cd/m2 | 12.7 lm W−1 |
Device structure | ITO/MoO3 (7nm)/NPB (85 nm)/ (PPQ)2Ir(acac):Ir(ppy)3:FIrpic:mCP/TAZ/LiF/Al [6] |
| Colour | White  |
| Max. EQE | 20.1% |
| Max. Power Efficiency | 41.3 lm W−1 |
| Device structure | ITO/PEDOT:PSS(40 nm)/mCP:PVK:OXD-7(33:33:22 wt%):(dfpmpy)2Ir(pic-N-O):(F4PPQ)2Ir(pic-N-O):(EO2- Cz-PhQ)2Ir(acac)*(12:0.25:0.15 wt%)(50-60 nm)/TmPyPB(20 nm)/LiF(1 nm)/Al(150 nm) [7] |
| Color | White  |
| Max. EQE | 11.45% |
| Max. Current Efficiency | 23.04 cd/A |
| Max. Power Efficiency | 8.04 lm W−1 |
*For chemical structure information, please refer to the cited reference.
Pricing
| Grade | Order Code | Quantity | Price |
| Sublimed (>99.5%) | M371 | 1 g | £89.00 |
| Sublimed (>99.5%) | M371 | 5 g | £338.00 |
| Unsublimed (>98.0%) | M372 | 5 g | £199.00 |
MSDS Documentation
mCP MSDS sheet
Literature and Reviews
- 100% phosphorescence quantum efficiency of Ir(III) complexes in organic semiconductor films, Y. Kawamura et al., Appl. Phys. Lett. 86, 071104 (2005); http://dx.doi.org/10.1063/1.1862777.
- Above 30% External Quantum Efficiency in Blue Phosphorescent Organic Light-Emitting Diodes Using Pyrido[2,3- b]indole Derivatives as Host Materials, C. Lee et al., Adv. Mater., 25, 5450–5454 (2013).
- Efficient organic light-emitting devices with platinum-complex emissive layer, X. Yang et al., Appl. Phys. Lett., 98, 033302 (2011); doi: 10.1063/1.3541447.
- Engineering of Mixed Host for High External Quantum Efficiency above 25% in Green Thermally Activated Delayed Fluorescence Device, B. Kim et al., Adv. Funct. Mater., 24, 3970–3977 (2014).
- Improved color stability in white phosphorescent organic light-emitting diodes using charge confining structure without interlayer, S-H. Kim et al., Appl. Phys. Lett. 91, 123509 (2007); http://dx.doi.org/10.1063/1.2786853.
- Manipulating Charges and Excitons within aSingle-Host System to Accomplish Efficiency/CRI/Color-Stability Trade-off for High-PerformanceOWLEDs, Q. Wang et al., Adv. Mater., 21, 2397–2401 (2009).
- Single emissive layer white phosphorescent organic light-emitting diodes based on solution-processed iridium complexes, W. Cho et al., Dyes and Pigments, 108, 115-120 (2014), doi:10.1016/j.dyepig.2014.04.033.
- Wide-Energy-Gap Host Materials for Blue Phosphorescent Organic Light-Emitting Diodes, S. Ye et al., Chem. Mater., 21 (7), 1333–1342 (2014).
- High efficiency phosphorescent organic light-emitting diodes using carbazole-type triplet exciton blocking layer, S. Kim et al., Appl. Phys. Lett., 90, 223505 (2007); http://dx.doi.org/10.1063/1.2742788.
- Deep blue phosphorescent organic light-emitting diodes with excellent external quantum efficiency, J. Park et al., Org. Electronics, 14 (12), 3228-3233 (2013), doi:10.1016/j.orgel.2013.09.017.
To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.
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实验需要请问有没有养THP-1细胞的同仁？能否寄一皿我，我在广州南方医科大学，不胜感激！
激光共聚焦的看活细胞皿哪里买呢
想问下各位大神，本人用皿养的PC-9GR细胞突然有大片飘起，也并没有成团状飘起，求解决方法？
如题~
已经基本养好了贴壁的原代细胞了，准备鉴定了，看到好多都在说细胞爬片的问题，我可以不做爬片直接在皿里操作吗？具体需要注意些什么呢？感谢各位大神
ps：大皿和6孔板里细胞密度、培养条件等等都几乎一样。
我看园子里有人提过类似的问题，但还没人给出答案，希望有经验或有想法的战友帮忙分析分析啊~谢谢！
同学说传代必须是一皿传多皿，一皿传一皿就不算传代~求高手指点~~
传代后5天，依然没有长满，怕影响活力，想传代和冻存，不知这样是否可以？？
做细胞实验快半年了，一直都还挺顺的，这次五一放完假回来，复苏一支HK2，操作都跟以前一样，没想到出了好多问题：
冻存方法：包裹棉花直接-80℃过夜，第二天转移到液氮
冻存时间：1个半月前冻存的细胞，密度保证没问题，冻存前状态也好
复苏方法：液氮取出后37℃水浴，约2分钟溶解，加入6倍体积的完全培养基，800转离心5分钟，弃去上清，1ml完全培养基重悬，转移入培养皿（进口一次性塑料培养大皿），补足完全培养基，培养箱培养
第二天看细胞全都没贴壁，但是也没死，聚集成团装飘着，没有污染。不想重新离心加重机械损伤，就一直试试看的心态放在培养箱里养着了。又重新复苏一支，还是一样的结果，全飘着没贴壁。不死心，就往前面复苏的那一皿里直接加了1ml的血清，相当于18%的血清比例，过了一天去看，这下细胞都贴壁了。没有另外添加血清的那一皿就还是没贴壁。
另外还有一支以前复苏的HK2，也是一样的方法复苏的，那次复苏很好，细胞基本没什么死的，也都贴壁了，养在皿里状态也不错，但是拿来铺板就还是不贴壁，同样的培基（10%血清），铺板就一个不贴，皿里就都可以贴上。
求助各位战友：
1、复苏不贴壁是为什么？
2、增加血清比例能使复苏的细胞贴壁，这样的细胞是不是可以认为状态并不好，以后的培养是不是要一直这么高比例的血清？还是可以培养一段时间逐步减少血清比例？
3、仍然是10%血清，为什么铺板就不贴壁，而皿里的就没事？是不是铺板的时候也要增加血清比例呢？那在板里干预的过程中是不是要一直保持高比例的血清培养？
4、我的冻存及复苏方法是否有错？我觉得我的HK2从形态、生长速度上来说状态应该是不错的，而且我已经更换了全新的培基、血清和双抗，重新配置了完全培养基，不知道为什么会出现这种不贴壁的问题
拜托各位集思广益，细胞实验已经为了这个不贴壁的问题停滞快2周，心急如焚啊，拜托各位！
